Supported Metal Complexes

Name: Supported Metal Complexes
Brand: Springer
SKU: 9789401088176
Price: 277.38 RON
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A New Generation of Catalysts

Autor: F.R. Hartley

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Editura: Springer

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It is now IS years since the first patents in polymer supported metal complex catalysts were taken o...

Informații despre carte

Autor

F.R. Hartley

Limbă

engleză

Legare

Carte - Carte broșată

Publicat

2011

Pagini

340

EAN

9789401088176

ISBN

9401088179

Enbook ID

02185641

Editura

Springer

Greutate

522

Dimensiuni

155 x 235 x 19

Descriere completă

It is now IS years since the first patents in polymer supported metal complex catalysts were taken out. In the early days ion-exchange resins were used to support ionic metal complexes. Soon covalent links were developed, and after an initially slow start there was a period of explosive growth in the mid to late 1970s during which virtually every homogeneous metal complex catalyst ever reported was also studied bound to a support. Both polymers and inorganic oxides were studied as supports, although the great preponderance of workers studied polymeric supports, and of these polystyrene was by far the commonest used. This period served to show that by very careful design polymer-supported metal complex catalysts could have specific advantages over homogeneous metal complex catalysts. However the subject was a complicated one. Merely immobilising a successful metal complex catalyst to a functionalised support rarely yielded other than an inferior version of the catalyst. Amongst the many discouraging results of the 1970s, there were more than enough results that were sufficiently encouraging to demonstrate that, by careful design, supported metal complex catalysts could be prepared in which both the metal complex and the support combined together to produce an active catalyst which, due to the combination of support and complex, had advantages of activity, selectivity and specificity not found in homogeneous catalysts. Thus a new generation of catalysts was being developed.

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Supported Metal Complexes

A New Generation of Catalysts

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