Carte S Sulfur-Nitrogen Compounds Norbert Baumann

S Sulfur-Nitrogen Compounds

Part 10a: Compounds with Sulfur of Oxidation Number II

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336.34 lei
This volume treats the acyclic sulfur(II)-nitrogen compounds with one-coordinate and two-coordinate...

Informații despre carte

Limbă
engleză
Legare
Carte - Carte broșată
Publicat
2013
Pagini
324
EAN
9783662063538
ISBN
3662063530
Enbook ID
02189922
Greutate
669
Dimensiuni
178 x 254 x 19

Descriere completă

This volume treats the acyclic sulfur(II)-nitrogen compounds with one-coordinate and two-coordinate sulfur. Sulfur imide (S=NH) and N-organyl-sulfur imides (S=NR) are unstable compounds which can be stabilized by coordination to transition metals or trapped, for example, by Ä2 + 4Ü cycloaddition with 1,3-butadiene. Among dithionitryl (1+) salts, only ÄS=N=SÜ+AsF6- has been studied extensively. Cycloaddition with alkenes and triple bond compounds produce 1,3,2-dithiazolium salts. Thiohydroxylamine, HSNH2, has been detected in the gas phase. Numerous examples of N,N-diorganyl-amino-halogeno-sulfanes (XSNR2, X = F, Cl, Br, I; R = organyl) and salts of the cation (XS)2N+ (X = Cl, Br) are known. N,N-Diorganyl-amino-chloro-sulfanes are important synthetic reagents.

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