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Carte N-Heterocyclic Carbenes Silvia Diez-Gonzalez

N-Heterocyclic Carbenes

From Laboratory Curiosities to Efficient Synthetic Tools

Autor: Silvia Diez-Gonzalez
Limbă: engleză
Legare: Copertă tare
Editura: Royal Society Of Chemistry
Disponibilitate: În depozitul extern
Expediem în 14-21 zile
910.68 lei
Over the last fifteen years, N-heterocyclic carbenes (NHCs) have mostly been used as ancillary ligan...

Informații despre carte

Autor
Silvia Diez-Gonzalez
Limbă
engleză
Legare
Carte - Copertă tare
Publicat
2010
Pagini
468
EAN
9781849730426
ISBN
1849730423
Enbook ID
05107218
Editura
Royal Society Of Chemistry
Greutate
834
Dimensiuni
241 x 165 x 30

Descriere completă

Over the last fifteen years, N-heterocyclic carbenes (NHCs) have mostly been used as ancillary ligands for the preparation of transition metal-based catalysts. Compared to phosphorus-containing ligands, NHCs tend to bind more strongly to metal centres, avoiding the necessity for the use of excess ligand in catalytic reactions. The corresponding complexes are often less sensitive to air and moisture, and have proven remarkably resistant to oxidation. Recent developments in catalysis applications have been facilitated by the availability of carbenes stable enough to be bottled, particularly for their use as organocatalysts. This book shows how N-heterocyclic carbenes can be useful in various fields of chemistry and not merely laboratory curiosities or simple phosphine mimics. NHCs are best known for their contribution to ruthenium and palladium-catalysed reactions but the scope of this book is much broader. The synthesis of NHC ligands and their corresponding metal complexes are covered in depth. Moreover, the biological activity of NHC-containing complexes, as well as an overview of their theoretical aspects are included. Such metal species are further examined, not only in terms of their catalytic applications, but also of their stereoelectronic parameters and reactivity/stability. Finally, special attention is given to the hot topic of organocatalysis. The book will be of interest to postgraduates, academic researchers and those working in industry.

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