Lewis Acid/Base-Stabilized Phosphanylalanes

Name: Lewis Acid/Base-Stabilized Phosphanylalanes
Brand: Sudwestdeutscher Verlag Fur Hochschulschriften AG
SKU: 9783838134116
Price: 258.76 RON
Availability: InStock

and Crystal Structure Determinations

Autor: Michael Bodensteiner

Limbă:

Legare: Carte broșată

Editura: Sudwestdeutscher Verlag Fur Hochschulschriften AG

Disponibilitate: În depozitul extern

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258.76 lei

This PhD thesis addresses two main topics. The synthetic chapter reports on the isomerization and ol...

Informații despre carte

Autor

Michael Bodensteiner

Limbă

engleză

Legare

Carte - Carte broșată

Publicat

2012

Pagini

EAN

9783838134116

ISBN

3838134117

Enbook ID

06889171

Editura

Sudwestdeutscher Verlag Fur Hochschulschriften AG

Greutate

150

Dimensiuni

152 x 229 x 6

Descriere completă

This PhD thesis addresses two main topics. The synthetic chapter reports on the isomerization and oligomerisation of Lewis acid/base-stabilized phosphanylalanes. NMR investigations - together with theoretical computations performed by Prof. Alexey Y. Timoshkin (University of St. Petersburg) - gave insight into the amine exchange in four-membered aluminium-phosphorus hetero-ring systems. The combination of analytical and computational methods also allowed the detailed clarification of the successive oligomerization at, for example, the tungsten pentacarbonyl- and trimethylamine-stabilized derivative. Furthermore, ethyldimethylamine was introduced as a new Lewis base and an unprecedented structural motif for aluminium phosphorus compounds was described. Finally, the reactivity of Lewis acid free derivatives of phosphanylalanes was explored and the scope was widened to stiba- and bismaboranes. In addition to the synthetic results, 132 crystal structures were determined. Crucial problems in crystallography are reported using selected examples, including: disorder, twinning, space group problems, solvent treatment and a modulated structure.

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Lewis Acid/Base-Stabilized Phosphanylalanes

and Crystal Structure Determinations

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Descriere completă

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