Laser-Induced Chemical Processes

Name: Laser-Induced Chemical Processes
Brand: Springer-Verlag New York Inc.
SKU: 9781468438659
Price: 580.2 RON
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Autor: Jeffrey I. Steinfeld

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Editura: Springer-Verlag New York Inc.

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The possibility of initiating chemical reactions by high-intensity laser exci tation has captured th...

Informații despre carte

Autor

Jeffrey I. Steinfeld

Limbă

engleză

Legare

Carte - Carte broșată

Publicat

2012

Pagini

288

EAN

9781468438659

ISBN

1468438654

Enbook ID

05185516

Editura

Springer-Verlag New York Inc.

Greutate

430

Dimensiuni

152 x 229 x 16

Descriere completă

The possibility of initiating chemical reactions by high-intensity laser exci tation has captured the imagination of chemists and physicists as well as of industrial scientists and the scientifically informed public in general ever since the laser first became available. Initially, great hopes were held that laser-induced chemistry would revolutionize synthetic chemistry, making possible "bond-specific" or "mode-specific" reactions that were impos sible to achieve under thermal equilibrium conditions. Indeed, some of the early work in this area, typically employing high-power continuous-wave sources, was interpreted in just this way. With further investigation, however, a more conservative picture has emerged, with the laser taking its place as one of a number of available methods for initiation of high-energy chemical transformations. Unlike a number of these methods, such as flash photolysis, shock tubes, and electron-beam radiolysis, the laser is capable of a high degree of spatial and molecular localization of deposited energy, which in turn is reflected in such applications as isotope enrichment or localized surface treatments. The use of lasers to initiate chemical processes has led to the discovery of several distinctly new molecular phenomena, foremost among which is that of multiple-photon excitation and dissociation of polyatomic molecules. This research area has received the greatest attention thus far and forms the focus of the present volume.

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