Carte Highly Luminescent Lanthanide Complexes with Specific Coordination Structures Kohei Miyata

Highly Luminescent Lanthanide Complexes with Specific Coordination Structures

Autor: Kohei Miyata
Limbă: engleză
Legare: Copertă tare
Disponibilitate: În depozitul extern
Expediem în 10-13 zile
551.82 lei
This thesis deals with strongly luminescent lanthanide complexes having novel coordination structure...

Informații despre carte

Autor
Limbă
engleză
Legare
Carte - Copertă tare
Publicat
2014
Pagini
91
EAN
9784431549437
ISBN
4431549439
Enbook ID
02531753
Greutate
318
Dimensiuni
164 x 243 x 13

Descriere completă

This thesis deals with strongly luminescent lanthanide complexes having novel coordination structures. Luminescent lanthanide complexes are promising candidates as active materials for EL devices, lasers, and bio-sensing applications. The organic ligands in lanthanide complexes control geometrical and vibrational frequency structures that are closely related to the luminescent properties. In most of the previous work, however, lanthanide complexes have high-vibrational frequency C H units close to the metal center for radiationless transition. In this thesis, the luminescent properties of lanthanide complexes with low-vibrational frequency C F and P=O units are elucidated in terms of geometrical, vibrational, and chemical structures. The author also describes lanthanide coordination polymers with both high thermal stability (decomposition point 300 C) and strong-luminescent properties (emission quantum yield 80%). The author believes that novel studies on the characteristic structures and photophysical properties of lanthanide complexes may open up a frontier field in photophysical, coordination and material chemistry.

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