Group 2 Mediated Dehydrocoupling

Name: Group 2 Mediated Dehydrocoupling
Brand: Springer International Publishing AG
SKU: 9783319370330
Price: 582.96 RON
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Autor: David J Liptrot

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Editura: Springer International Publishing AG

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582.96 lei

This book presents an in-depth study into the utility of s-bond metathesis in Group 2 mediated react...

Informații despre carte

Autor

David J Liptrot

Limbă

engleză

Legare

Carte - Carte broșată

Publicat

2016

Pagini

162

EAN

9783319370330

ISBN

3319370332

Enbook ID

15194099

Editura

Springer International Publishing AG

Greutate

2818

Dimensiuni

155 x 235 x 11

Descriere completă

This book presents an in-depth study into the utility of s-bond metathesis in Group 2 mediated reactivity. A comprehensive introduction defines the state of the art in both Group 2 mediated catalysis and dehydrocoupling. Structural investigations giving rise to a range of mixed s-block metal hydrides including a remarkable dodecabimetallic decahydride are then described. Subsequent extensive mechanistic work focussing on both silicon-nitrogen and boron-nitrogen dehydrocoupling gives insights into both congeneric effects down Group 2 and ligand effects centring upon magnesium. These studies show the striking effects of these factors, as well as the electronic nature of the hydridic coupling partner. Finally, the unprecedented introduction of single-electron transfer steps into Group 2 catalytic manifolds is described. The use of the stable radical TEMPO to induce single-electron transfer to substituents bound to Group 2 centres coupled with s-bond metathesis allows a novel hydrogen release from silanes.

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Group 2 Mediated Dehydrocoupling

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