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Carte Functionalised Mesoporous Zirconium Titanium Oxide Materials Massey de los Reyes

Functionalised Mesoporous Zirconium Titanium Oxide Materials

Autor: Massey de los Reyes
Limbă: engleză
Legare: Carte broșată
Editura: LAP Lambert Academic Publishing
Disponibilitate: La editor doar la comandă
Expediem în 17-27 zile
405.71 lei
A series of hybrid mesoporous materials were synthesised through the functionalisation of pre-formed...

Informații despre carte

Autor
Massey de los Reyes
Limbă
engleză
Legare
Carte - Carte broșată
Publicat
2012
Pagini
204
EAN
9783846540114
Enbook ID
06917859
Editura
LAP Lambert Academic Publishing
Greutate
304
Dimensiuni
152 x 229 x 12

Descriere completă

A series of hybrid mesoporous materials were synthesised through the functionalisation of pre-formed porous zirconium titanium oxide phases using a range of commercially available phosphonic acids. A fundamental study on the hydrolytic stability and chemical durability of these materials in aqueous acidic conditions were conducted. Polyphosphonic acids have been recognised as the most stable surface species. With potential use of these materials for the nuclear industry in view, a study of the irradiation stability of the un-functionalised zirconium titanium oxides were conducted. Changes to the structural morphology were found from physical characterisation techniques evidencing the overall decrease in surface area, pore volume and mass density with increased doses. A similar irradiation study was also carried out for functionalised zirconium titanium oxides. Structural characterisation revealed a drop in surface area, pore diameter and pore volume, along with a rise in mass density after exposure to high levels of radiation. A loss of functionalised phosphonate molecules was also observed by thermal analysis under the same conditions.

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